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(1)   Qi   Wang, Miao Lv, Jianping Liu, Yang Li, Hongen Cao,* Xu Zhang, and   Qing Xu,* Efficient   Synthesis of Quinazolinones by Transition Metal-Free Direct Aerobic Oxidative   Cascade Annulation of Alcohols with o-Aminoarylnitriles,   ChemSusChem 2019, DOI:10.1002/cssc.201900265. (SCI新一区，IF   7.411)

(2)           Haicheng Liu, Jianping Liu,* Xiaokai   Cheng, Xiaojuan Jia, Lei Yu, Qing Xu,* DMSO-triggered complete   oxygen transfer leading to accelerated aqueous hydrolysis of organohalides   under mild conditions, ChemSusChem,   2019, DOI:10.1002/cssc.201802138.   (SCI新一区，IF   7.411).

(3)           Chao Chen, Xu Zhang, Hongen Cao, Fang   Wang, Lei Yu* and Qing Xu*, Iron-Enabled Utilization of Air as   the Terminal Oxidant Leading to Aerobic Oxidative Deoximation by   Organoselenium Catalysis, Adv. Synth. Catal. 2019, 361   (3), 603-610. DOI:   10.1002/adsc.201801163. (SCI二区)

(4)     Xiantao Ma, Qing Xu,*   Huan Li, Chneliang Su, Lei Yu, Xu Zhang, Hongen Cao and Li-Biao Han,*   Alcohol-Based Michaelis-Arbuzov Reaction: an Efficient and Environmentally-Benign   Way for C-P(O) Bond Formation. Green Chem. 2018, 20 (15),   3408-3413. (SCI新一区，IF   8.506). DOI:   10.1039/c8gc00931g

Highlighted   by Green Chem.   as Back Cover Paper.

(5)     Bin Feng, Yang Li, Huan Li, Xu   Zhang, Huamei, Xie, Hongen Cao, Lei Yu, and Qing Xu,*   Specific N-Alkylation of Hydroxypyridines Achieved by a Catalyst- and   Base-Free Reaction with Organohalides. J. Org. Chem. 2018,   83 (12), 6769–6775.   (SCI-II) DOI:10.1021/acs.joc.8b00787

(6)     Yonghong Liu,^† Daliang   Tang,^† Kuanhong Cao, ^† Lei Yu,* Jie Han* and Qing   Xu* (^†These authors contributed equally), Probing   the support   effect at the molecular   level in polyanilines-supported   palladium nanoparticles-catalyzed   Ullmann reaction   of aryl   iodides.   J. Catal. 2018, 360, 250-260. (SCI新一区) DOI:   10.1016/j.jcat.2018.01.026

(7)     Dongliang Zhang,^† Yaping   Huang,^†, Erlei Zhang,^† Rong Yi,^† Chao Chen,^†   Lei Yu,* and Qing Xu* (^†These authors contributed   equally), Pd/Mn Bimetallic Relay Catalysis for Aerobic Aldoxime Dehydration   to Nitriles, Adv. Synth. Catal. 2018, 360 (4), 784-790.   (SCI新一区，影响因子6.567). DOI:10.1002/adsc.201701154

(8)     Yaqi Yang, Zihang Ye,   Xu Zhang, Yipeng Zhou, Xiantao Ma, Hongen Cao, Huan Li, Lei Yu, and Qing   Xu,^* Efficient dehydrative alkylation of thiols   with alcohols catalyzed by alkyl halides, Org. Biomol. Chem.   2017, 15 (45),   9638-9642. (SCI-II) DOI:   10.1039/c7ob02461d

(9)     Song Yao, Kaijing Zhou, Jiabing Wang,   Hongen Cao, Lei Yu, Jianzhang Wu,* Peihong Qiu,* Qing Xu.*   Synthesis of 2-Subsitituted Quinazolines by CsOH-Mediated Direct Aerobic Oxidative   Cyclocondensation of 2-Aminoarylmethanols with Nitriles in Air. Green   Chem. 2017,   19 (13), 2945-2951 (SCI新一区，IF   8.506). DOI:   10.1039/ C7GC00977A

Highlighted   by X-mol: http://www.x-mol.com/news/9424

(10) Xiantao Ma, Lei Yu, Chenliang Su,*   Yaqi Yang, Huan Li, and Qing Xu*,   Efficient Generation of C-S Bonds via a Byproduct-Promoted Selective Coupling   of Alcohols, Organohalides, and Thiourea.   Adv. Synth. Catal. 2017, 359,   1649-1655. (SCI新一区，影响因子6.567). DOI   10.1002/adsc.201700227.

(11) Jianhui Chen,† Yang Li,† Shuangyan Li,   Jianping Liu,* Fei Zheng, Zhengping Zhang, and Qing Xu*,   Aldehyde/Ketone-Catalyzed Highly Selective Synthesis of 9-Monoalkylated Fluorenes   by Dehydrative C-Alkylation with Primary and Secondary Alcohols, Green   Chem. 2017, 19 (1), 623-628. (SCI新一区，IF   8.506) DOI:   10.1039/c6gc02518h

(12) Xiang Ren, Qihang Guo, Jianhui Chen,   Hujun Xie,* Qing Xu* and Zhan Lu*. Visible-Light Promoted   Distereodivergent Intramolecular Oxyamidation of Alkenes. Chem.   Eur. J. 2016,   22 (52), 18695-18699. (SCI-II, IF: 5.731) DOI:   10.1002/chem.201603977

(13) Xiaokai Cheng, Bo Yang, Xingen Hu, Qing   Xu, and Zhan Lu,* Visible-Light-Promoted   Metal-Free Aerobic Oxidation of Primary Amines to Acids and Lactones. Chem.   Eur. J. 2016,   22 (49), 17566-17570. (SCI-II, IF:   5.731) DOI:   10.1002/chem.201604440

(14) Yang Li, Haonan Chen, Jianping Liu,*   Xujun Wan, and Qing Xu*, Clean Synthesis of Primary to Tertiary   Carboxamides by CsOH-Catalyzed Aminolysis of Nitriles in Water, Green   Chem. 2016, 18 (18),   4865–4870. (SCI-II, IF 8.506) DOI:   10.1039/C6GC01565D

(15)            

(16) Wang, Wei-Min; Liu, Li-Juan; Yao,   Lan; Meng, Fan-Jie; Sun, Yong-Ming; Zhao, Chang-Qiu; Xu,   Qing; Han, Li-Biao. Stereospecific Preparations of P-Stereogenic   Phosphonothioates and Phosphonoselenoates. J. Org. Chem.   2016, 81 (15),   6843-6847. (SCI-II，IF: 4.721) DOI: 10.1021/acs.joc.6b01192

(17) Jianping Liu,* Chao Wang, Xiantao   Ma, Xinkang Shi, Xin Wang, Huan Li, and Qing   Xu.* Simple Synthesis of Benzazoles by   Substrate-Promoted CuI-Catalyzed Aerobic Oxidative Cyclocondensation of o-Thio/Amino/Hydroxyanilines   and Amines under Air. Catal. Lett.   2016, 146 (10),   2139-2148 (SCI-III, IF 2.294) DOI:   10.1007/s10562-016-1818-2

(18) Qing Xu,* Huamei Xie, Er-Lei Zhang, Xiantao Ma, Jianhui   Chen, Xiao-Chun Yu, and Huan Li. Selective Catalytic Hoffmann N-Alkylation of   Poor Nucleophilic Amines and Amides with Catalytic Amounts of Alkyl Halides. Green.   Chem. 2016, 18 (14), 3940-3944. (SCI-II, IF:   8.506). DOI:   10.1039/C6GC00938G

(19) Xiantao   Ma, Quan Liu, Xiaojuan Jia, Chenliang Su* and Qing Xu*,   Efficient Synthesis of Unsymmetrical Heteroaryl Thioethers and Chalcogenides   by Alkali Hydroxide-Mediated S_NAr Reactions of Heteroaryl Halides   and Dichalcogenides, RSC Adv. 2016, 6 (62), 56930-56935. (IF 3.84). DOI: 10.1039/C6RA10517C

(20) Xiantao   Ma, Chenliang Su, Qing Xu*, N-Alkylation by   hydrogen autotransfer reactions (Invited Review) in Hydorgen   Transfer Reactions (Eds.: Guillena, G.; Ramón, D. J.), Top.   Curr. Chem. 2016,   374:27, 1-74. (IF 4.464).   DOI: 10.1007/s41061-016-0027-1

(21) Qiang Li, Tieqiao Chen, Qing   Xu,* Li-Biao Han.* Rhodium- and Iridium-Catalyzed Asymmetric Addition of Optically   Pure P-Chiral H-Phosphinates to Aldehydes Leading to Optically Active   α-Hydroxyphosphinates. Chem.   Eur. J. 2016,   22 (18), 6213-6217. (SCI-II, IF: 5.731) DOI:dx.doi.org/10.1002/chem.201600115

Highlighted   by Synfacts: Synfacts   2016, 12(7), 0710

(22) Xiaohui Li, Shuangyan Li, Qiang Li, Xu   Dong, Yang Li, Xiaochun Yu, Qing Xu.* Efficient and Practical   Catalyst-Free-Like Dehydrative N-Alkylation of Amines and Sulfinamides   with Alcohols Initiated by Aerobic Oxidation of Alcohols under Air. Tetrahedron 2016,   72 (2), 264-272 (SCI-III,   IF: 2.641). DOI:   10.1016/j.tet.2015.11.016.

(23) Lei Yu,* Yaping Huang, Zheng Wei,   Yuanhua Ding, Chenliang Su,* Qing Xu.* Heck   Reactions Catalyzed by Ultrasmall and Uniform Pd Nanoparticles Supported on   Polyaniline. J. Org. Chem.2015,   80 (17),   8677–8683 (SCI-II，IF: 4.721). DOI:   10.1021/acs.joc.5b01358

被X-MOL化学咨询平台亮点摘录：http://www.x-mol.com/news/1350

(24) Lei   Yu,* Jianqing Ye, Xu Zhang, Yuanhua Ding,   Qing Xu.* Recyclable (PhSe)2-catalyzed selective oxidation of   isatin by H2O2: a practical and waste-free access to isatoic anhydride under   mild and neutral conditions. Catal. Sci. Technol.   2015, 5 (10),   4830-4838 (SCI-II, IF: 5.426). DOI:   10.1039/C5CY01030F

(25) Lei Yu,* Mingxuan Liu,   Fenglin Chen and Qing Xu.* Heterocycles from   Methylenecyclopropanes, Org. Biomol. Chem. 2015, 13,   8379-8392 (SCI-III, IF: 3.562, 外封面论文). DOI:   10.1039/C5OB00868A.

(26) Xinkang Shi, Junmei Guo, Jianping Liu,   Mingde Ye, Qing Xu.^* Unexpectedly   Simple Synthesis of Benzazoles by t-BuONa-Catalyzed Direct Aerobic   Oxidative Cyclocondensation of o-Thio/Hydroxy/Aminoanilines   with Alcohols under Air. Chem.   Eur. J. 2015,   21 (28), 9988-9993 (SCI-II, IF: 5.731). DOI:   10.1002/chem.201501184

Highlighted   by Synfacts: Synfacts   2015, 11(9), 0925

Highlighted   by Advances   in Engineering as a   Key Scientific Article contributing to excellence in engineering, scientific   and industrial research

(27) Shuangyan Li, Xiaohui Li, Qiang Li,   Qiaochao Yuan, Xinkang Shi, Qing Xu.* Structure-Dependent   Tautomerization Induced Catalyst-Free Autocatalyzed N-Alkylation of   Heteroaryl Amines with Alcohols. Green Chem.   2015, 17 (6), 3260-3265 (SCI-II, IF: 8.02).   DOI:10.1039/C4GC02542C

(28) Qing   Xu,* Huamei Xie,** Pingliang Chen,** Lei   Yu, Jianhui Chen, Xingen Hu* (** These authors contribute equally to this   work). Organohalides-Catalyzed Dehydrative   O-Alkylation between Alcohols: A Facile Etherification   Method for Aliphatic Ether Synthesis. Green Chem.   2015, 17 (5), 2774-2779 (SCI-II, IF: 8.02). DOI:10.1039/C5GC00284B

被X-MOL化学咨询平台亮点摘录：http://www.x-mol.com/news/1171

(29) Xu   Zhang, Jianqing Ye, Lei Yu,* Xinkang Shi, Ming Zhang, Qing   Xu,* Mark Lautens. Organoselenium-Catalyzed Baeyer-Villiger Oxidation   of α,β-Unsaturated Ketones by Hydrogen Peroxide to Access Vinyl Esters. Adv.   Synth. Catal. 2015,   357 (5), 955-960 (SCI-II,   IF: 5.663).  DOI:   10.1002/adsc.201400957

   被Organic   Chemistry Portal摘录：http://www.organic-chemistry.org/Highlights/2016/14March.shtm

(30) Qiang Li, Yao Huang, Tieqiao Chen,   Yongbo Zhou,* Qing Xu, Shuang-Feng Yin,* Li-Biao Han. Copper-Catalyzed Aerobic Oxidative Amination of sp³C–H   Bonds: Efficient Synthesis of 2-Hetarylquinazolin-4(3H)-ones. Org. Lett. 2014,   16 (14),   3672–3675 (SCI-II, IF: 6.364).  DOI:10.1021/ol501454j

(31) Lei Yu,* Jun Wang, Hongen Cao, Kehong   Ding, Qing Xu*, A Review on Catalyzed   Dimerization of Acrylonitrile, Chin.   J. Org. Chem. 2014, 37 (7),   1986-1991 (SCI, IF: 0.917).    DOI:10.6023/cjoc201405004

(32) Xiaojuan Jia, Lei Yu, Jianping Liu,   Qing Xu,* Marcel Sickert, Lianhui Chen, and Mark Lautens.* Sulfur-silicon   bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical   thioethers by replacing fluoride catalysis and fluorinated substrates in S_NAr   reactions, Green Chem. 2014, 16 (7), 3444-3449 (SCI-II,   IF: 8.02). DOI:10.1039/C4GC00535J

(33) Lei   Yu,* Jun Wang, Xu Zhang, Hongen Cao, Genling Wang, Kehong Ding, Qing   Xu*, Mark Lautens. Practical preparation   of 2-methyleneglutaronitrile via an efficient and highly selective   head-to-tail dimerization of acrylonitrile catalyzed by low-loading   tricyclohexylphosphine. RSC Adv.   2014,   4 (37), 19122-19126 (SCI-III, IF: 3.84). DOI:10.1039/C4RA02810D

(34) Haonan   Chen, Wujie Dai, Yi Chen, Qing Xu,* Jianhui Chen, Lei Yu,   Yajuan Zhao, Mingde Ye, Yuanjiang Pan.* Efficient and selective nitrile   hydration reaction in water catalyzed by unexpected dimethylsulfinyl anion   generated in situ from CsOH and DMSO.   Green Chem. 2014, 16 (4), 2136-2141 (SCI-II,   IF: 8.02). DOI:10.1039/C3GC42310G

(35) Lei Yu,* Hongyan Li, Xu Zhang, Jianqing   Ye, Jianping Liu, Qing Xu,* Mark Lautens.   Organoselenium-Catalyzed Mild Dehydration of Aldoximes:   An Unexpected Practical Method for Organonitrile Synthesis. Org. Lett.   2014, 15   (3), 1346-1349 (SCI-II,   IF: 6.364). DOI:10.1021/ol500075h

被Organic   Chemistry Portal摘录：http://www.organic-chemistry.org/abstracts/lit4/413.shtm

(36) Qing Xu,* Jianhui Chen, Haiwen Tian, Xueqin   Yuan, Shuangyan Li, Chongkuan Zhou, Jianping Liu. Catalyst-Free   Dehydrative α-Alkylation of Ketones with Alcohols: Green and Selective   Autocatalyzed Synthesis of Alcohols and Ketones. Angew. Chem. 2014, 126 (1), 229-233; Angew. Chem.   Int. Ed. 2014, 53 (1), 225-229 (SCI-I, IF:   13.734). DOI:10.1002/ange.201308642; DOI:10.1002/anie.201308642

浙江省基金网站报道：http://www.zjnsf.gov.cn/h/01/news_view.aspx?appid=GUDD5EB45D5C95010591E580385CA982CF8

(37) Lei   Yu,* Yulan Wu, Hongen Cao, Xu Zhang, Xinkang Shi, Jie Luan, Tian Chen, Yi Pan,   Qing Xu.* Facile Synthesis of 2-Methylenecyclobutanones via   Ca(OH)₂-Catalyzed Direct Condensation of Cyclobutanone with   Aldehydes and (PhSe)₂-Catalyzed Baeyer-Villiger Oxidation to   4-Methylenebutanolides. Green Chem. 2014, 16   (1), 287-293 (SCI-II,   IF: 8.02).   DOI:10.1039/C3GC41562G

(38) Erlei Zhang, Haiwen Tian, Sendong Xu,   XiaochunYu, Qing Xu.* Iron-Catalyzed Direct Synthesis of Imines   from Amines or Alcohols and Amines via Aerobic Oxidative Reactions under Air.   Org. Lett. 2013, 15 (11), 2704-2707   (SCI-II, IF: 6.364). DOI:10.1021/ol4010118

被Organic   Chemistry Portal摘录：www.organic-chemistry.org/abstracts/lit4/049.shtm

(39) Quan Liu, Zhongxiang Lu, Wenfei Ren,   Kaibo Shen, Yu Wang, Qing Xu.* Efficient   Synthesis of Unsymmetrical Heteroaryl Ethers by a Transition Metal-Free C-O   Cross-Coupling Reaction of Activated and Unactivated Heteroaryl Chlorides   with Alcohols and Phenols. Chin. J Chem. 2013,   31 (6),   764-772 (SCI, IF: 0.917). DOI:10.1002/cjoc.201300120

(40) Bo Huang, Haiwen Tian, Shoushuai Lin,   Meihua Xie, Xiaochun Yu,* Qing Xu.* Cu(I)/TEMPO-Catalyzed   Aerobic Oxidative Synthesis of Imines Directly from Primary and Secondary   Amines under Ambient and Neat Conditions. Tetrahedron Lett. 2013,   54 (22), 2861-2864 (SCI-III, IF: 2.379). DOI:10.1016/j.tetlet.2013.03.098

(41) Qing Xu,*   Yong-Bo Zhou, Chang-Qiu Zhao, Shuang-Feng Yin, Li-Biao Han.^* Transition   Metal-Catalyzed Efficient and Green Transformations of P(O)−H Compounds to   Functional Organophosphorus Compounds. Mini-Rev. Med. Chem. 2013,   13 (6), 824-835 (SCI-III,   IF: 2.903). DOI:10.2174/1389557511313060005

(42) Qing Xu,*   Jianhui Chen, Quan Liu. Aldehyde-Catalyzed   Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with   Alcohols. Adv. Synth. Catal. 2013,   355 (4), 697-704 (SCI-II, IF: 5.663).   DOI:10.1002/adsc.201200996

(43) Lei Yu,* Yulan Wu, Tian Chen, Yi Pan, Qing   Xu.* Direct Synthesis of Methylene-1,2-dichalcogenolanes via Radical   [3+2] Cycloaddition of Methylenecyclopropanes with Elemental Chalcogens. Org.   Lett. 2013, 15 (1), 144-147 (SCI-II, IF: 6.364).    DOI:10.1021/ol3031846

(44) Qing Xu,*   Qiang Li, Xiaogang Zhu, Jianhui Chen. Green and Scalable Aldehyde-Catalyzed   Transition Metal-Free Dehydrative N-Alkylation of Amides and Amines   with Alcohols. Adv. Synth. Catal. 2013,   355 (1), 73-80 (SCI-II,   IF: 5.663). DOI:10.1002/adsc.201200881

被Organic   Chemistry Portal摘录：http://www.organic-chemistry.org/Highlights/2013/28October.shtm

(45) Qing Xu,*   Qiang Li. Recent Advances of Transition Metal-Catalyzed Aerobic Dehydrative   Reactions of Alcohols and Amines and Related Reactions. Chin. J. Org.   Chem. 2013,   33 (1), 18-35 (SCI,   IF: 0.741).  DOI:10.6023/cjoc201208016

(46) Haiwen Tian, Xiaochun Yu, Qiang Li,   Jianxin Wang, Qing Xu.* General,   Green, and Scalable Synthesis of Imines from Alcohols and Amines by a Mild   and Efficient Copper-Catalyzed Aerobic Oxidative Reaction in Open Air at Room   Temperature. Adv. Synth. Catal. 2012,   354 (14-15), 2671-2677 (SCI-II, IF: 5.663).   DOI:10.1002/adsc.201200574

Cited and commented by Science-2013-339-43 as an exceptionally   good method for imine preparation from alcohols and amines)

(47) Qing Xu,   Chang-Qiu Zhao, Yong-Bo Zhou, Shuang-Feng Yin, Li-Biao Han.* Transition   Metal-Catalyzed Transformations of P(O)-H Bonds. Chin. J. Org. Chem.   2012, 32 (10), 1761-1775   (SCI, IF: 0.741; 外封面论文).   DOI:10.6023/cjoc201207024

(48) Xiaochun Yu, Lan Jiang, Qiang Li,   Yuanyuan Xie, Qing Xu.* Palladium-Catalyzed N-Alkylation   of Amides and Amines with Alcohols Employing the Aerobic Relay Race   Methodology. Chin. J. Chem. 2012, 30 (10), 2322-2332 (SCI,   IF: 0.917). DOI:10.1002/cjoc.201200462

(49) Qiang   Li, Songjian Fan, Qing Sun, Haiwen Tian,   Xiaochun Yu, Qing Xu.* Copper-Catalyzed N-Alkylation of Amides   and Amines with Alcohols Employing the Aerobic Relay Race Methodology. Org.   Biomol. Chem. 2012, 10 (15), 2966-2972 (SCI-III,   IF: 3.562). DOI:10.1039/C1OB06743E

Highlighted   by Org. Biomol. Chem. as Outside Front Cover Paper.

Featured   in the top 10% of the most highly cited articles published   in the latest Impact Factor window 2011-2012）

(50) Shiheng Liao, Kangkang Yu, Qiang Li,   Haiwen Tian, Zhengping Zhang, Xiaochun Yu, Qing Xu.* Copper-Catalyzed   C-Alkylation of Secondary Alcohols and Methyl Ketones with Alcohols Employing   the Aerobic Relay Race Methodology. Org. Biomol. Chem. 2012, 10 (15), 2973-2978 (SCI-III, IF:   3.562). DOI:10.1039/C1OB06739G

Highlighted   by Org. Biomol. Chem. as Front Cover Paper.

Featured   in the top 10% of the most highly cited articles published   in the latest Impact Factor window 2011-2012）

(51) Xiaochun Yu, Chuanzhi Liu, Lan Jiang, Qing   Xu.* Manganese Dioxide Catalyzed N-Alkylation of Sulfonamides   and Amines with Alcohols under Air. Org. Lett. 2011,   13 (23), 6184-6187 (SCI-II, IF: 6.364). DOI:10.1021/ol202582c

被Organic   Chemistry Portal摘录: http://www.organic-chemistry.org/abstracts/lit3/476.shtm

(52) Lan Jiang, Luolu Jin, Haiwen Tian,   Xueqin Yuan, Xiaochun Yu,* Qing Xu.* Direct and Mild   Palladium-Catalyzed Aerobic Oxidative Synthesis of Imines from Alcohols and   Amines under Ambient Conditions. Chem. Commun. 2011, 47   (38), 10833-10835 (SCI-II, IF: 6.834). DOI:10.1039/c1cc14242a

“十一五”浙江省自然科学基金优秀论文、浙江省自然科学学术奖三等奖

(53) Chuanzhi Liu, Shiheng Liao, Qiang Li,   Sunlin Feng, Qing Sun, Xiaochun Yu,* Qing Xu.* Discovery and   Mechanistic Studies of a General Air-Promoted Metal-Catalyzed Aerobic N-Alkylation   Reaction of Amides and Amines with Alcohols. J. Org. Chem. 2011, 76   (14), 5759-5773 (SCI-II, IF: 4.721). DOI:10.1021/jo200862p

(54) Sun Lin Feng, Chuan Zhi Liu, Qiang Li;   Xiao Chun Yu, Qing Xu.* Rhodium-Catalyzed Aerobic N-Alkylation   of Sulfonamides with Benzylic Alcohols. Chin. Chem. Lett. 2011, 22   (9), 1021-1024.   (SCI, IF: 1.21) DOI:10.1016/j.cclet.2011.03.014

《中国化学快报》2011年度优秀论文、《中国化学快报》2013年度高被引论文

(55) Chuanzhi Liu, Xufeng Zang, Baohua Yu,   Xiaochun Yu,* Qing Xu.* Microwave-Promoted   TBAF-Catalyzed S_NAr Reaction of Aryl Fluorides and ArSTMS: an   Efficient Synthesis of Unsymmetrical Diaryl Thioethers. Synlett,   2011, (8),   1143-1148 (SCI-III, IF: 2.655). DOI:10.1055/s-0030-1259959

(56) Qing Xu,   Ruwei Shen, Yutaka Ono, Ritsuko Nagahata, Shigeru Shimada, Midori Goto,   Li-Biao Han.* A New Oxapalladacycle Generated via Ortho C-H Activation of Phenylphosphinic   Acid: Efficient Catalyst for Markovnikov-Type Additions of E-H Bonds to   Alkynes. Chem. Commun. 2011, 47 (8),   2333-2335 (SCI-II, IF: 6.834). DOI:10.1039/c0cc03436c

被Organic Chemistry   Portal摘录: www.organic-chemistry.org/Highlights/2011/31October.shtm

被Labome摘录:   http://www.ncbi.nlm.nih.gov/pubmed/21161095

(57) Qing Xu,   Han, Li-Biao.* Metal-catalyzed   additions of H-P(O)   bonds to carbon-carbon   unsaturated   bonds. J.   Organometallic Chem. 2011, 696 (1), 130-140 (SCI,   IF: 2.0).

DOI:10.1016/j.jorganchem.2010.08.043

(58) Qing Xu,* Li-Biao   Han.* Transition Metal-Catalyzed Selective   Hydrophosphorylation Reactions. Scientia Sinica Chimica, 2010, 40 (7), 802-826.

(59) Qing Xu,   Chang-Qiu Zhao, Li-Biao Han.* Stereospecific   Nucleophilic Substitution   of Optically Pure   H-Phosphinates: A General Way for the   Preparation of Chiral P-Stereogenic Phosphine Oxides. J. Am. Chem. Soc. 2008,   130 (38), 12648-12655 (SCI-I, IF: 12.113). DOI:10.1021/ja804412k

该工作被日本《化学工业日报》和研究同行高度评价

本人参与Han教授的该系列工作2015年4月和9月分别获得日本科学技术奖（日本文部科学大臣表彰）和筑波奖励奖（つくば奨励賞）

(60) Qing Xu,   Li-Biao Han.* Palladium-Catalyzed Asymmetric   Hydrophosphorylation of Norbornenes. Org.   Lett. 2006,   8 (10), 2099-2101 (SCI-II, IF: 6.364). DOI:10.1021/ol060568y

(61) Qing Xu,   Xian Huang,* Jingqi Yuan. Facile Synthesis of β-Organotellurobutenolides   via Electrophilic Tellurolactonization of α-Allenoic Acids. J.   Org. Chem. 2005, 70 (17), 6948-6951 (SCI-II, IF: 4.721). DOI:10.1021/jo050564r

(62) Qing Xu,   Xian Huang.* Cis-Carbocuperation of Acetylenic Sulfoxides and   Corresponding Applications in the Regio- and Stereoselective Synthesis of   Polysubstituted Vinyl Sulfoxides. Tetrahedron Lett. 2004,   45 (29), 5657-5660. (SCI-III,   IF: 2.379)   DOI:10.1016/j.tetlet.2004.05.141

(63) Qing   Xu, Xian Huang,* Jun Ni. Hydrotelluration   and Carbotelluration of Acetylenic Sulfoxides: Regio- and Stereoselective   Preparation of α- and β-Organotellurovinyl Sulfoxides. Tetrahedron   Lett. 2004, 45(14), 2981-2984 (SCI-III,   IF: 2.379).    DOI:10.1016/j.tetlet.2004.02.064

授权专

利

(1)           Li-Biao Han,   Qing Xu. Method for Producing Optically Active Phosphate   Compounds. Japanese   Patent JP2007-137831A.

(2)           Li-Biao Han,   Qing Xu. Method for Producing Optically Active Phosphorus   Compound. Japanese   Patent JP2008-69103A.

(3)           徐清、余小春、田海雯，《一种亚胺类化合物的合成方法》，中国发明专利：ZL201210007393.X   (2014-07-16).

(4)           徐清、陈建辉、郑飞、张正平，《一种单烷基芴的合成方法》，中国发明专利：ZL201310072756.2   (2014-11-19).

(5)           徐清、余小春、李强，《一种醇与胺脱水合成胺类化合物的方法》，中国发明专利：ZL201210061107.8   (2014-12-24).

(6)           徐清、陈建辉、田海雯、袁雪勤、周崇款，《一种取代酮的绿色合成方法》，中国发明专利：ZL201310168583.4   (2014-12-24).

(7)           徐清、余小春、张二磊、徐义兰、周勇、俞磊，《一种由醛肟或醛和羟胺制备一级酰胺的方法》，中国发明专利：ZL201310016400.7   (2015-02-18).

(8)           徐清、陈浩楠、陈逸、戴武杰、仇晶晶，《一种由腈制备杂环化合物的绿色方法》，中国发明专利：ZL201310245469.7   (2015-02-25).

(9)           徐清、李双艳、李强，《一种氨基噻唑化合物的脱水烷基化方法》，中国发明专利：ZL201310088068.5   (2015-04-15).

(10)       徐清、胡新根、陈平良，《一种对称和非对称脂肪醚的合成方法》，中国发明专利：ZL201310073115.9   (2015-06-10).

(11)       徐清、田海雯、尹新林、张鹏飞，《一种铜催化醇氧化制备醛和酮的绿色方法》，中国发明专利：ZL201310245470.X   (2015-06-24).

(12)       徐清、陈浩楠、万旭军，《一种制备二级和三级取代酰胺的方法》，中国发明专利：ZL201210499023.2   (2015-06-24).

(13)       徐清、廖诗亨，《一种甲基酮的α-烷基化方法》，中国发明专利：ZL201210348380.9   (2015-07-01).

(14)       徐清、史鑫康、郭俊梅、周斌，《一种苯并噻唑杂环化合物的绿色合成方法》，中国发明专利：ZL201310399108.8   (2015-07-08).

(15)       徐清、谢华楣、张二磊、陈建辉,《一种制备N-烷基吡啶酮的绿色合成方法》，中国发明专利：ZL201410722906.4   (2017-04-12).

(16)       徐清、谢华楣、张二磊、陈建辉,《一种由醇和胺制备胺衍生物的绿色方法》，中国发明专利：ZL201410722806.1   (2017-06-20)

(17)       徐清、杨雅淇、谢华楣，《一种由醇和硫醇制备非对称硫醚的绿色方法》，中国发明专利：ZL201610329337.6   (2017-11-10)。

(18)       徐清、史鑫康、陈敏方, 《喹喔啉杂环化合物的合成方法》，中国发明专利：ZL201510803720.6   (2018-03-23).

(19)       徐清、李双艳、陈建辉、袁雪琴、张正平,《一种杂环甲基化合物的脱水C-烷基化方法》，中国发明专利：ZL201410723220.7   (2018-09-04)。

(20)       徐清、马献涛、苏陈良，《一种非对称杂芳基硫醚的合成方法》，中国发明专利：ZL201610381700.9   (2018.10.26).

(21)       徐清、姚松、仇佩红、吴建章、李欢、王佳兵,   《一种2-取代喹唑啉类杂环化合物的合成方法》，中国发明专利：ZL201610410717.2   (2018-10-16).

代表

论著

徐清*、吴华悦，《亨利反应(Henry   Reaction)》（胡跃飞教授、林国强院士主编《现代有机反应》第七卷第三章, pp 93-155），化学工业出版社，2013年。

主
  要
  项
  目

（1）   国家自然科学基金面上项目“醇的可控活化策略机理研究及其在碳-碳和碳-杂键绿色构建中的应用”（项目号21672163，2017.1-2020.12，主持）

（2）   浙江省自然科学基金委杰出青年基金项目“醇的绿色活化方法研究及其在碳-碳和碳-杂化合物合成中的应用”（项目号LR14B020002，2014.01-2018.12，主持）

（3）   国家自然科学基金青年基金项目“亚胺的绿色合成及其在有机药物中间体合成中的应用研究”（2014.01-2016.12，参与）

（4）   浙江省自然科学基金一般项目“亚胺的绿色合成及其在药物中间体合成中的应用研究”（2013.01-2015.12，参与）

（5）   国家自然科学基金青年基金项目“光学活性磷手性磷氢化合物合成法开发及其绿色导入研究”（2010.01-2012.12，负责人，已结题）

（6）   教育部第40批留学回国人员科研启动基金“光学活性磷手性磷氢化合物合成法开发及其绿色导入研究”（负责人）

（7）   浙江省自然科学基金一般项目“环化官能团化反应合成有机碲代杂环化合物及其应用研究”（2010.06-2013.06，负责人，以优秀成绩结题）

（8）   浙江省钱江人才计划特殊急需类D类项目“光学活性磷手性化合物绿色合成法开发及其在药物合成中的应用”（2010.01-2012.12，负责人）

（9）   浙江省高等学校优秀青年教师资助计划项目“官能团化环化反应研究及其在复杂分子合成中的应用”（2009.09-2011.10，负责人，已结题）

获
  奖
  及
  荣
  誉

（1）         2016年12月，入选江苏省企业创新类“双创人才”（江苏恒安化工有限公司）；

（2）         2015年12月，入选江苏省淮安市“淮上英才计划” 创新创业领军人才（江苏恒安化工有限公司）；

（3）         2015年10月， 论文“Unexpectedly   Simple Synthesis of Benzazoles by t-BuONa-Catalyzed Direct Aerobic   Oxidative Cyclocondensation of o-Thio/Hydroxy/Aminoanilines   with Alcohols under Air”(Chem.   Eur. J. 2015,   21, 9988)被 Advances   in Engineering 评为“a   Key Scientific Article contributing to excellence in engineering, scientific   and industrial research”；

（4）       2014年10月，入选浙江省151人才工程第二层次；同年12月直接列入温州市“551人才工程”第一层次；

（5）       2014年8月，论文“Copper-Catalyzed   N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic   Relay Race Methodology”(Org.   Biomol. Chem. 2012,   10 (15), 2966-2972) 被评为2011-2012影响因子周期Org.   Biomol. Chem.杂志“top 10% of the   most highly cited articles”；

（6）         2014年8月，论文“Copper-Catalyzed   C-Alkylation of Secondary Alcohols and Methyl Ketones with Alcohols   Employing the Aerobic Relay Race Methodology”(Org.   Biomol. Chem. 2012,   10 (15), 2973-2978) 被评为2011-2012影响因子周期Org.   Biomol. Chem.杂志“top 10% of the   most highly cited articles”；

（7）         2014年5月，论文“Palladium-Catalyzed   N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay   Race Methodology”(Chin.   J. Chem. 2012,   30, 2322-2332)入选 Chin. J. Chem.杂志   “one of the most accessed papers in Top 25 from 5/2013 to 4/2014”；

（8）       2014年5月，入选第十三届“温州市十大杰出青年”；

（9）       2014年，获浙江省自然科学基金委杰出青年基金；

（10）   2013年12月，论文“Rhodium-Catalyzed   Aerobic N-Alkylation of Sulfonamides with Benzylic Alcohols”(Chin.   Chem. Lett. 2011, 22   (9), 1021-1024)被评为《中国化学快报》2013年度高被引论文；

（11）   2013年11月，入选温州市“580海外精英引进计划”；同时入选“温州市特聘专家”；

（12）   2013年9月，入选浙江省151人才工程第三层次；

（13）   2013年8月，论文“Palladium-Catalyzed   N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay   Race Methodology”(Chin.   J. Chem. 2012,   30, 2322-2332)入选 Chin. J. Chem.杂志“one   of the most accessed papers from 8/2012 to 7/2013”；

（14）   2013年2月，论文“Rhodium-Catalyzed   Aerobic N-Alkylation of Sulfonamides with Benzylic Alcohols”(Chin.   Chem. Lett. 2011, 22   (9), 1021-1024)被评为《中国化学快报》2011年度优秀论文；

（15）   2012年12月，《室温空气条件下直接温和的钯催化醇和胺有氧氧化合成亚胺的方法》获浙江省自然科学学术奖三等奖（排名1/4）；

（16）   2012年12月，《过渡金属催化醇与胺有氧反应机理研究及应用》获浙江省高等学校优秀科研成果奖三等奖（排名1/2）；

（17）   2012年12月，入选首届澳门新葡平台网址8883“学生科技创新十佳指导教师”；

（18）   2012年11月，入选温州市“新世纪551人才工程”第二层次；

（19）   2012年9月，论文“Direct   and Mild Palladium-Catalyzed Aerobic Oxidative Synthesis of Imines from   Alcohols and Amines under Ambient Conditions” (Chem. Commun.   2011, 47, 10833)被评为“十一五”浙江省自然科学基金优秀论文；

（20）   2009年11月，入选浙江省高等学校优秀青年教师资助。

优

秀

毕

业

生

优秀硕士毕业生：

(1)   14级硕士 李洋：发表 Green Chem.等论文，考取南京理工大学博士研究生；

(2)   14级硕士 程骁恺：发表 Chem. Eur. J.等论文，考取浙江大学博士研究生；

(3)   12级硕士 李晓慧（女）：发表Tetrahedron、Green Chem.等论文，考取厦门大学博士研究生；

(4)   11级硕士 陈建辉：发表 Angew. Chem.、 Green Chem.、Adv. Synth. Catal.等论文；在校期间获11-12年度研究生二等奖学金、12-13年度研究生一等奖学金、2013年研究生国家奖学金、2014年浙江省优秀毕业生等荣誉称号；免试推荐攻读浙江大学博士研究生（导师：陆展研究员）；

(5)   10级硕士 田海雯（女）：发表 Adv.   Synth. Catal.、Angew.   Chem.、Chem.   Commun.、Org.   Biomol. Chem.等论文；在校期间获10-11、11-12年度研究生一等奖学金、2012年研究生国家奖学金、2013年校级优秀毕业生、华峰院长奖等荣誉称号；考取复旦大学2013级博士研究生（导师：周锡庚教授）；

(6)   10级硕士 吴于兰（女，扬州大学13届毕业生，与俞磊副教授联合培养）：发表Org. Lett.、Green Chem. 等论文；获2012年研究生国家奖学金；扬大化学化工学院优秀毕业生；江苏某大型药企工作；

(7)   09级硕士 李强：发表 Adv.   Synth. Catal.、Org.   Biomol. Chem.、J.   Org. Chem.等论文；考取湖南大学12级博士研究生（导师：韩立彪教授）；

优秀本科毕业生：

(1)   06级本科生 臧旭峰：本课题组10届本科毕业论文学生，期间发表Synlett、J. Chem. Res.等论文；在校期间多次获得一等、二等奖学金、三好学生、优秀学生干部、优秀学生党务干部、校优秀毕业生等荣誉称号；考取华南理工大学10级硕士研究生，现转攻读博士研究生（导师：曹德榕教授）；

(2)   06级本科生 邵羽裳（女）：本课题组10届本科毕业论文学生；考取华东师范大学10级硕士研究生（导师：李艳忠教授）；

(3)   06级本科生 谢建江：本课题组10届本科毕业论文学生；在校期间多次获得奖学金；考取南京理工大学10级硕士研究生（导师：李峰副教授）；现就职于三门核电有限公司；

(4)   08级本科生 崔巍：本课题组12届本科毕业论文学生；考取华南理工大学12级硕士研究生（导师：曹德榕教授）；

(5)   08级本科生 周勇：本课题组12届本科毕业论文学生；2011年国家励志奖学金、12级华东理工大学和上海有机所联合培养硕士研究生（导师：游书力研究员）；

(6)   08级本科生 汪家宏：本课题组12届本科毕业论文学生；2011年国家励志奖学金、考取华东理工大学12级硕士研究生；

(7)   08级本科生 张俊：本课题组12届本科毕业论文学生；考取华东师范大学12级硕士研究生；

(8)   09级本科生 罗明部：本课题组13届本科毕业论文学生；考取福州大学13级硕士研究生；

联系

方式

本课题组常年招收有机化学专业研究生，同时与深圳大学合作招收绿色有机合成与催化方向博士后（待遇优厚、见下文链接），也欢迎热爱科研与学术的本科生同学参与本科毕业论文、省新苗人才计划、大学生创新创业训练计划等大学生科研创新项目！

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