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祝贺王舜老师指导的研究生王德猛在ACS Appl. Mater. Interfaces上发表学术论文
添加时间:2013年09月02日 浏览:
Synthesis of Au-Decorated Tripod-Shaped Te Hybrids for Applications in the Ultrasensitive Detection of Arsenic
Novel Au-decorated Te hybrids with a tripod-shaped planar microstructure were prepared through a two-step hydrothermal process: the synthesis of Te single crystals and the subsequent self-sacrificial reaction of Te template with HAuCl
4
. Based on the influences of reaction temperature and solvent compositions on the as-obtained microstructures, a plausible mechanism was proposed to account for the formation of the tripod-shaped Te and Au/Te crystals. The as-prepared Au/Te hybrids have the sensitivity of 6.35 μA/ppb in the electrochemical detection of As(III), which represents the highest sensitivity reported in literature. The Au/Te sensor also has a low detection limit of 0.0026 ppb and could work in complex mixtures containing As(III), Cu(II) and other heavy metal ions, exhibiting excellent selectivity on As(III) and Cu(II) ions. The enhanced electrocatalytic property may be attributed to the synergetic interactions between the noble metal and semiconductor and the presence of a large number of active sites on the hybrids surface.
原文:
http://pubs.acs.org/doi/abs/10.1021/am401205w
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祝贺杨小平老师和黄少铭老师在JACS上发表学术论文
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祝贺唐天地课题组在燃油精制催化新材料的设计与合成领域取得新进展