祝贺向卫东和梁晓娟老师指导研究生在Materials Research Bulletin上发表学术论文

标题：Optical properties of bimetallic Au-Cu nanocrystals embedded in glass

Abstact：Bimetallic gold-copper and gold-copper solid solutions nanocrystals (NCs) with orthorhombic morphologies were successfully embedded in sodium borosilicate glass; these materials were fabricated via a facile and synthetic sol-gel technique. Microstructural investigations demonstrate that the Au-Cu intermetallic nanostructure is generated in the glass host. Z-scan technique was applied to reveal the third-order nonlinear optical properties of the as-obtained glasses at the wavelength of 800 nm. The as-synthesized glasses exhibit similar nonlinear behaviors with reverse saturation absorption effects and self-focusing performances. The third-order nonlinear susceptibility χ(3) values were optimized by tuning the sizes of the Au-Cu NCs. The χ(3) of Au-Cu(1), Au-Cu(2) and Au-Cu(3) measured to be 3.1 × 10-12, 5.4 × 10-12, and 4.4 × 10-12 esu for the single-pulse energy of 1 μJ. We have discussed the nonlinear optical mechanism of Au-Cu sodium borosilicate glass that may be due to the quantum confinement effects and surface plasmon resonance effects.

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